Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. 3 Effective date : 12.14.2014 Page 2 of 7 Hexane (n-Hexane) Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Colorless liquid with a faint benzene-like odor. (1R)-2alpha-Chloro-2-methylcyclohexane-1alpha-ethanol | C9H17ClO | CID 11229099 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Major hazard facilities. Physical Description. May cause respiratory tract irritation. Vapor may accumulate in container headspace resulting in flammability hazard. Most important hazard(s): Xi - Irritant: R 36/37/38 - Irritating to eyes, respiratory system, and skin. Articles of 4 … Product name METHYLCYCLOHEXANE CAS-No. ECOLOGICAL INFORMATION A. 4-Methylcyclohexanemethanol (MCHM, systematic name 4-methylcyclohexylmethanol) is an organic compound with the formula CH 3 C 6 H 10 CH 2 OH. Found inside – Page 57Office of Hazardous Materials Operations ... anhydrous packaging , 173.143 Methylcyclohexane packaging , 173.118 , 173.119 Methylcyclopentane packaging ... Found inside – Page 69Cyclohexane , methylcyclohexane , and tetrahydrona phthalene were decomposed and the gaseous products were analyzed . The apparatus used is described in ... SHOP MEK Molecular Formula C. 7. Aspiration hazard if swallowed - can enter lungs and cause damage. Toxic to aquatic life with long lasting effects. 1-CHLORO-1-METHYLCYCLOHEXANE SDS details show. Each label features a GHS hazard pictrogram based on the chemical being labeled. Get medical attention. Found inside – Page 668... 1,1,1 - Trichloroethane Methyl cyclohexane Methyl cyclohexanol ( at 30 ° C ) o - Methyl cyclohexanone Methyl ethyl ketone ( 2 - Butanone or MEK ) Methyl ... MSDS Creation Date: 1/07/1998 Revision #4 Date: 11/20/2008 The information above is believed to be accurate and represents the best information currently available to us. Vapors may cause dizziness or suffocation. Class IB Flammable Liquid: Fl.P. Found inside – Page 275... see 2-methoxyethyl acetate Methyl chloride 74-87-3 — —2 Methyl chloroform (1,1,1-trichloroethane) 71-55-6 350 1900 Methylcyclohexane 108-87-2 500 2000 ... CAS 108-87-2. Reactivity Profile. Found inside – Page 297... Methyl Cyanide Methyl Cyanoacetate Methyl - 2 - Cyanoacrylate Methyl Cyanoethanoate Methylcyclohexane 3 - Methyl Cyclohexanol 4 - Methyl Cyclohexanol ... Toluene vapor has a sharp or sweet odor, which is a sign of exposure. Classified as a saturated higher alicyclic primary alcohol.Both cis and trans isomers exist, depending on the relative positions of the methyl (CH 3) and hydroxymethyl (CH 2 OH) groups on the cyclohexane ring. Exposure to Methylcyclohexane can cause you to feel dizzy and lightheaded. May cause drowsiness or dizziness. Causes skin irritation. Methyl methacrylate is irritating to the skin, eyes, and mucous membranes in humans. Aspiration hazard May be fatal if swallowed and enters airways. ChemSpider ID 11085. Explosion characteristics of methylcyclohexane (MCH)-methanol- and toluene-methanol-air mixtures were investigated in a closed vessel at 0.1 MPa covering wide blending ratio range.The explosion hazard was evaluated by determining important explosion parameters. Aspiration hazard: - May be fatal if swallowed and enters airways C. Numerical measures of toxicity(such as acute toxicity estimate):-12. This record has not been tagged. The form summarizes the safety and ADA related items that need to be documented. SAFETY DATA SHEET Creation Date 14-May-2009 Revision Date 26-January-2018 Revision Number 4 1. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Found inside – Page 134... o - isopropoxyphenyl ester Methyl chloride Methyl 2 - cyanoacrylate Methylcyclohexane Methylcyclohexanol o - Methylcyclohexanone Methylcyclopentadienyl ... By law you have the right to know what chemicals Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. NIST/TRC Web Thermo Tables (WTT) NIST Standard Reference Subscription Database 3 - Professional Edition Version 2-2012-1-Pro This web application provides access to a collection of critically evaluated thermodynamic property data for pure compounds with a primary focus on organics. Aquatic, terrestrial organisms toxicity: Fish - [Methylcyclohexane] : LC50 5.8 ㎎/ℓ 96 hr Crustaceans - [Methylcyclohexane] : LC50 3.3 ㎎/ℓ 96 hr Algae - Not available 8 Page 4-Methylcyclohexanemethanol (MCHM, systematic name 4-methylcyclohexylmethanol) is an organic compound with the formula CH 3 C 6 H 10 CH 2 OH. Rat liver microsomes fortified with NADPH were shown to hydroxylate methylcyclohexane. 8.3 Individual protection measures, such as personal protective equipment (PPE) Eye/face protection. Methylcyclohexane(CAS NO.64742-48-9) 42 Synonyms: Acrylic Resins 12.5 Others 0.5 Remarks: OZONE SAFE FORMULA B.-PHYSICAL DATA 179.6 - 230ºF 82 - 110ºC N/A ℉ N/A ºC N/A ºF N/A ºC 752ºF 400ºC 23ºF -5ºC Flammable Limits in Air (% by volume) Lower 1% Upper 8% Classified as a saturated higher alicyclic primary alcohol.Both cis and trans isomers exist, depending on the relative positions of the methyl (CH 3) and hydroxymethyl (CH 2 OH) groups on the cyclohexane ring. 4-MCHM is a colorless liquid, which has a sweet smell, like licorice. Hazard Statements: Highly flammable liquid and vapour. Found insideHPLCNUv ; OSHA ( # 55 ] 1 ppm = 4.62 mg / m Sp . Gr ( 81 ° F ) : 1.10 Class IIIA Combustible Liquid Methylcyclohexane CH , CH , Cyclohexylmethane ... GHS Label elements, including precautionary statements Pictogram Hazard statement(s) None found. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. C6H11CH3. Inhalation or contact with material may irritate or burn skin and eyes. Found inside – Page 59... METHYLACRYLONITRILE METHYLAL METHYLAMINE 2 - METHYLAZ IRIDINE METHYLAZOXYMETHANOL ACETATE METHYLCYCLOHEXANE METHYCYCLOHEXANOL METHYLCYCLOPENTAD I ENYL ... MCHM is used in washing coal, helping separate the burnable fossil fuel from the … Skin May be harmful if absorbed through skin. 1.3 Details of the supplier of the safety data sheet Company RCI LABSCAN LIMITED. Commercial samples of MCHM consists of … Found inside – Page 336... 1,000 ppm 700 ppm 108872 Methylcyclohexane 10,000 ppm 1,200 ppm [LEL] 25639423 Methylcyclohexanol 10,000 ppm 500 ppm 583608 o-Methylcyclohexanone 2,500 ... Found inside – Page 165... butyrate methyl carbonate methylcyclohexane 4-methylcyclohexene methylcyclopentane methyldichlorosilane 2-methyl-4-ethylhexane 3-methyl-4-ethylhexane ... If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Found inside – Page 914914 MIQ740 METHYLCYCLOHEXANE SYNS: ADHERE D COAPT [] O.-CYANOACRYLIC ACID METHYL ESTER D 2-CYANOACRYLIC ACID, METHYL ESTER [. Vapours may cause drowsiness and dizziness. for the hazard and dose-response assessment in IRIS pertaining to chronic exposure to cyclohexane. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Company Fisher Scientific One Reagent Lane Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Skin:Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid. Aspiration hazard May be fatal if swallowed and enters airways. Chronic:Chronic exposure may cause liver damage. Browse Methylcyclohexane and related products at MilliporeSigma. Found inside – Page 199... Ethylene glycol Ethylene oxide Methanol Methanol Methylcyclohexane Methylcyclohexane Styrene Toluene Toluene CHO CH , 02 CH САН , CH CH C6H2 C . H2 CH . Never give anything by mouth to an unconscious person. Getting started; Methylcyclohexane Msds; Methylcyclohexane Msds - China Manufacturers, Factory, Suppliers. Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. This document communicates information relating to test and assay use only and may not be applicable for any unauthorized use. The stated limit of 1,500 ppm is based on a review of the safety data. Flammable liquids, Category 2 Skin irritation, Category 2 Aspiration hazard, Category 1 Specific target organ toxicity \u2013 single exposure, Category 3 Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2 hazard ratings are primarily based Chemical name :methylcyclohexane Other means of Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Found inside – Page 368... ST 450 ppm ( 2450 mg / m3 ) Methyl - 2 - cyanoacrylate TWA 2 ppm ( 8 mg / mo ) , ST 4 ppm ( 16 mg / mo ) Methylcyclohexane TWA 400 ppm ( 1600 mg / m ? ) ... ANSI/EN/150000014291/Version 5.0 0032691126/0004233552 HM/S@ rating involves data interpretations that may vary from company to company. Material Safety Data Sheet or SDS for Methylcyclohexane 806147 from Merck for download or viewing in … (Robert H. Perry, 1997) According to (PubChem,1997) and 4.0 Material and Apparatus (PubChem,2002), the boiling point of methylcyclohexane and toluene are 101°C and 111°C respectively. Found inside – Page 474... p - Xylene 0 - Xylene n - Nonane n - Decane n - Undecane Methylcyclohexane TNMHC 440 274 466 209 122 105 107 114 5,010 9.67 19.0 49.1 25.1 11.5 23.4 ... Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. Safety Data Sheet for Methylcyclohexane 806147. An allergic response to dermal exposure may develop. Found inside – Page 117... Methylcyclohexane 3 - Methyl - heptane n - Nonane 1 - Methylcyclohexene 1 - Octene B - Pinene Limonene Toluene P- , m - Xylene 1,3,5 - Trimethylbenzene ... In other settings, aliphatic saturated hydrocarbons are mostly unreactive. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Methyl methacrylate is irritating to the skin, eyes, and mucous membranes in humans. Science Supply Store offers Lab Supplies and Equipment, ECO Funnels, Nalgene Lab Bottles, Pharmacy Vials and Containers, Safety Storage Cabinets and Safety Cans 2. Major hazard facilities are locations such as oil refineries, chemical plants and large fuel or chemical storage sites where large quantities of hazardous materials are stored, handled or processed. Links with this icon indicate that you are leaving the CDC website.. A key element in this process is the documentation of safety related work. methylcyclohexane 100 108-87-2 Ingredient name % CAS number There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. S 02 - Keep out of the reach of children. Monoisotopic mass 96.093903 Da. Perfluoro (Methylcyclohexane) [CAS# 355-02-2] - GHS Pipe Marking Label. Chemsrc provides 4-methylcyclohexene(CAS#:591-47-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. You can also browse global suppliers,vendor,prices,Price,manufacturers of Methylcyclohexane(108-87-2). Page 2 of 12 MSDS - Heptane accumulate static charges which may cause an … 4-MCHM is a colorless liquid, which has a sweet smell, like licorice. Additional Data The model WHS Regulations define a MHF as a facility: 4-Methylcyclohexene is used in the synthesis of an enantiomerically pure oxaliplatin derivative, {(1R,2R,4R)-4-Methyl-1,2-cyclohexanediamine}oxalatoplatinum(II), which exhibits good anticancer activity.It is also used in the preparation of N,N-diethyldithiocarbamate functionalized 1,4-polyisoprenes. Get medical attention. Section 4 - First Aid Measures. That's where 4-methylcyclohexane methanol, MCHM for short, comes in. Commercial samples of MCHM consists of … Found inside – Page 48... organic Methyl chloroform Methylcyclohexane 0 - Methylcyclohexanone Tolucne Tributyl phosphate Trichloroacetic acid TCA ) IMPACT ON RECOMMENDED ... S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. : AC126580000; AC126580010; AC126580025; AC126580050; AC126580100; AC126580250 chemBlink provides samples of SDS, Safety Data Sheets, for Perfluoro(methylcyclohexane), CAS 355-02-2 Methylcyclohexane. Colorless liquid with a faint, benzene-like odor. Hazard Summary Methyl methacrylate is used in the manufacture of resins and plastics. Articles of 3 … Found inside – Page 1062Methylcyclohexane is a suitable solvent to reduce the hazardous properties of the peroxyester. See other DIACYL PEROXIDES, PEROXYCARBONATEESTERS 3031. FIRST AID MEASURES General advice Consult a physician. The safety and amenity of residents living in areas near major hazard facilities is a priority for the Victorian Government, along with ensuring the continued viability and growth of these industries. Respiratory effects have been reported in humans following acute (short-term) and chronic (long-term) inhalation exposures. An allergic response to dermal exposure may develop. Vapour/air mixtures are explosive. Used commercially as a solvent for cellulose derivatives particularly with othersolvents, and as an organic intermediate in organic synthesis. 4-Methylcyclohexanol, mixture of cis and trans. Respiratory effects have been reported in humans following acute (short-term) and chronic (long-term) inhalation exposures. Prolonged or repeated skin contact can cause cracking and drying of exposed areas. H304 (89.36%): May be fatal if swallowed and enters airways [Danger Aspiration hazard] H315 (80.85%): Causes skin irritation [ Warning Skin corrosion/irritation] H319 (80.85%): Causes serious eye irritation [ Warning Serious eye damage/eye irritation] 4. special hazards none aerosol storage code 3 national fire protection association (nfpa) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. CAS No: 2890-62-2; Molecular Weight: 140.22; Molecular Formula: C 9 H 16 O; Names and Identifiers Properties Safety and Handling Precursor and Product Computational chemical data The Methylcyclohexane, with the CAS registry number 108-87-2 and EINECS registry number 203-624-3, is also called methyl-cyclohexane. Visit ChemicalBook To find more Methylcyclohexane(108-87-2) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Found inside – Page 36Residence time, min wt% Compound 1.76 5.67 Pentane 1.99 7.46 Hexane 2.58 8.47 Heptane 2.83 1.87 Methylcyclohexane 3.44 3.51 Toluene 3.84 6.55 Octane 4.43 ... 4 methylcyclohexane methanol msds pdf 4-Methylcyclohexanemethanol (MCHM, systematic name 4- methylcyclohexylmethanol) is an Eastman Chemical Company’s MSDS for ” crude” (unpurified) MCHM, as supplied by NPR, reports an oral LD of mg/ kg and a dermal LD Product Name. Identification::: Supplier's details : Flammable Gas Mixture: 1,2,3-Trimethylbenzene / 1,2,4-Trimethylbenzene / Benzene / Cyclohexane / Ethyl Benzene / Hexane / Methane / Methylcyclohexane / Ingestion Aspiration hazard if swallowed - can enter lungs and cause damage. : 3 Packing Group: II Hazardous Statement: H225-H304-H315-H336-H411 Precaution Statement: P210-P261-P273-P301 + P310-P331 3 Effective date : 12.14.2014 Page 2 of 7 Hexane (n-Hexane) Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com MATERIAL SAFETY DATA SHEET Revision Date: 10/19/2005 MSDSUSA! Inhalation Remove to fresh air. H. 12. 4-methylcyclohexane methanol (or 4-MCHM) is a chemical that is used in certain industries for purification of coal for metallurgical operations and blending gasoline. Found insideStrong oxidizers Char ; CSi GC7FID ; 2831 74 1 ppm = 5.55 mg / m3 Cyclohexylmethane , Hexahydrotoluene Methylcyclohexane CHỊCH MW : 98.2 BP : 214 ° F Sol ... If not breathing, give artificial respiration. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. 4-methylcyclohexane methanol (or 4-MCHM) is a chemical that is used in certain industries for purification of coal for metallurgical operations and blending gasoline. Short term exposure to solvents can irritate eyes, lungs and skin and may cause headaches, nausea, dizziness and light-headedness. Explosion characteristics of methylcyclohexane (MCH)-methanol- and toluene-methanol-air mixtures were investigated in a closed vessel at 0.1 MPa covering wide blending ratio range.The explosion hazard was evaluated by determining important explosion parameters. Methylcyclohexane. Identification Product Name Methylcyclohexane Cat No. Found insideFlam Limit 1.2-6.7 Flash Pt 25 154 154 154 147 H9 Tox CAS # Chemical Name LS Methylcyclohexane 108-87-2 2 2 3 - Methyl Cyclohexanol 25639-42-3 2 2 4 ... Breathing Methylcyclohexane can irritate the nose and throat. MSDS Name: Methylenecyclohexane Catalog Numbers: AC325510000, AC325510010 Synonyms: None known. Synonyms: Hexahydrotoluene. May cause skin irritation. Found inside – Page 1686Several states have set guidelines or standards for methyl cyclohexane in ambient air[60] ranging from 16 - 20 mg/m3 (North Dakota) to 27 mg/m3 (Virginia) ... Handle in accordance with good industrial hygiene and safety practice. MATERIAL SAFETY DATA SHEET Methylcyclohexane Version 1.4 Revision Date 2012-03-05 MSDS Number:100000014163 2/13 GHS-Labeling Symbol(s) : Signal Word : Danger Hazard Statements : H225: Highly flammable liquid and vapor. Chemsrc provides 3-Methyl-1-cyclohexene(CAS#:591-48-0) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Gas concentrations are in percent by volume. Found inside – Page 79Oil and Hazardous Materials Spills Branch ... The oils are dissolved in methylcyclohexane and cooled to 77 ° K . Methylcyclohexane is a good solvent that ... Found inside – Page 821... 269 Metal working tools, hazards, 694-695 Metameric colours, hazards of, 233 Methods of protection in flammable atmospheres, 560 Methyl cyclohexane, ... Saturated aliphatic hydrocarbons, such as METHYLCYCLOHEXANE, may be incompatible with strong oxidizing agents like nitric acid. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use Toluene is a clear, colorless liquid which becomes a vapor when exposed to air at room temperature. Eyes May cause eye irritation. Found inside – Page 225... 12 (isopentane) methyl cyclohexane 0.27 1 .96 3.5 1.2 6.7 44 methyl forrnate 0.4 4.5 23 n-pentane 0.28 2.55 3.3 1.5 7.8 46 12 2-methyl pentene 0.18 2.72 ... Wash thoroughly after handling. The MSDS is a form which lists the hazardous ingredients in a product. The chemical 4-methylcyclohexane methanol is a greasy substance commonly described as smelling like licorice (or sometimes coconut oil). 2890-62-2) SDS. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. H315: Causes skin irritation. ... Methylcyclohexane 11.8 1,180 Methylisobutylketone. Label First Aid: Aspiration hazard. Found inside... Methylcyclohexane Methylcyclohexanol 4.8E-03 125,000 52.753 7.2 | | |,42 | 55.57] Q3,584 Font Chemical Name Notes Chromyl chloride f Arsine [c] Coball. CAS 108-87-2, EC Number 203-624-3, chemical formula C₆H₁₁CH₃. Reactivity Profile. 4-Methylcyclohexanol, mixture of cis and trans. Use only with adequate ventilation. Found inside – Page 14... DIMETHYLANILINE 2256 CYCLOHEXENE 2265 DIMETHYLFORMAMIDE 2271 5 - METHYL - 3 - HEPTANONE 2291 LEAD 2294 MONOMETHYL ANILINE 2296 METHYLCYCLOHEXANE 2297 O ... Keep container closed. Found inside – Page 2158Use only nonsparking tools and equipment, especially when opening and closing containers of methylcyclohexane. Shipping: UN2296 Methylcyclohexane, Hazard ... Precautionary statement(s) None found. Found inside – Page 129... (1,1,1-Trichloroethane) 71 - 55 - 6 350 1900 Methylcyclohexane 108 - 87 - 2 500 2000 Methylcyclohexanol 25639 - 42 - 3 100 470 o-Methylcyclohexanone 583 ... Inhalation May be harmful if inhaled. Found inside – Page 465Treon JF , Crutchfield WE Jr , Kitzmiller KV : The physiological response of animals to cyclohexane , methylcyclohexane , and certain derivatives of these ... Methylcyclohexane Revision Date 26-Jan-2018 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived. Found inside – Page 13OSHA 137-05-3 [#55] AS7000000 OSHAt none SpGrt.81'F):110 1 ppm = 454 mg/m3 Class lllA Combustible Liquid Methylcyclohexane Cyclohexylmetnane NlOSH 1200 ... 108-87-2 Product code AR1121, GP1121, RP1121 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Chemical for analysis and production. 3-Methylcyclohexene. It is not intended to be a comprehensive treatise on the chemical or toxicological nature of cyclohexane. May cause toxic effects if inhaled or absorbed through skin. Fire will produce irritating, corrosive and/or toxic gases. Show this safety data sheet to the doctor in attendance.Move out of dangerous area. Contaminated food or hands can also lead to solvents being swallowed. Found inside – Page ii... the research at the University , was a member of the Fuel Branch , Fuel , Lubrication , and Hazards Division , Air Force Aero Propulsion Laboratory . Safety Information and Hazard Symbols Symbol: GHS02, GHS07, GHS08, GHS09 Signal Word: Danger UN No. NOTE: NO FURTHER DISCOUNT FOR THIS PRINT PRODUCT- OVERSTOCK SALE -Significantly reduced listprice The official Emergency Response Guidebook (ERG) is a guide for use by transporters, firefighters, police, and other emergency services ... Wash hands before breaks and at the end of workday. It is highly soluble in organic solvents but slightly soluble in water due to its oily consistency. - Find MSDS or SDS, a COA, data sheets and more information. New state planning policy for major hazard facilities. This encourages the consideration of low cost safety and other operational improvements. Your employer is required by law to give you a copy of the MSDS, if you ask for it. It is highly soluble in organic solvents but slightly soluble in water due to its oily consistency. Found inside – Page 333... immediately and thoroughly decontaminate personnel Hazards : Description ... METHYLCYCLOHEXANE 3 0 FLAMMABLE UN 2296 Shipping Name : Methylcyclohexane. The binary 4.1 Materials mixture of methylcyclohexane-toluene is used in the 1. What are the hazards? Health Hazard Harmful if inhaled or swallowed. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract and skin. Narcotic effects and dermititis. (USCG, 1999) Reactivity Profile Saturated aliphatic hydrocarbons, such as METHYLCYCLOHEXANE, may be incompatible with strong oxidizing agents like nitric acid. Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity, single exposure Category 3 narcotic effects ... Methylcyclohexane 108-87-2 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Microsomes prepared from rats pretreated with phenobarbital hydroxylated methylcyclohexane at a 4 to 5 fold greater rate than controls; phenobarbital pretreatment also caused a 4 to 5 fold increase in the "type 1" substrate binding difference spectrum. Saturated aliphatic hydrocarbons, such as Methylcyclohexane, may be incompatible with strong oxidizing agents like nitric acid. Causes serious eye damage. Other OSHA standards that generally apply to hazardous substances include the Hazard Communication standard and the Respiratory Protection standard . Keep your hazardous materials labeled and facility safe with this durable and highly noticeable GHS Pipe Marking Label. Found inside – Page 714... 2-mcthylpentane 3-methylhexane 3-methylpentane octane nonane decane dodecane tridecane methylcyclohexane heptane tetradecane 2-methylheptane cyclohexane ... Found inside – Page 413Mutat Res 188 : 97-104 , 1987 METHYLCYCLOHEXANE CAS : 108-87-2 C - H4 mined concentrations of methyl cyanoacrylate in an adhesive developed respiratory symptoms after 1 month on the job . ? Eleven weeks after stopping work , the ... Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. NO open flames, NO sparks and NO smoking. METHYLCYCLOHEXANE: ICSC: 0923: Hexahydrotoluene Cyclohexylmethane: July 1997: CAS #: 108-87-2: UN #: 2296 EC Number: 203-624-3 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Highly flammable. Found inside – Page 91... Chemie (France) Solvay Group (Belgium) Methyl chlorosilane General Electric Rhodia (France) Methylcyclohexane Atofina (France) Chevron Phillips Chemical ... However, ECHA If you would like to purchase MEK or Acetone please call (800)-563-1305 or purchase our products conveniently online: SHOP ACETONE. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. (Methylcyclohexane) Additional Information Repeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level - 250 mg/kg(Methylcyclohexane) Repeated dose toxicity - Rat - male and female - Inhalation(Methylcyclohexane) RTECS: GV6125000 Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Unconsciousness and death may occur at higher exposures. Average mass 96.170 Da. 1-Acetyl-1-methylcyclohexane (CAS No. Hazards identification Material Safety Data Sheet Isopropyl Alcohol, 50-100% v/v - 4 - Skin: Wear appropriate gloves to prevent skin exposure. 1-methyl-1-cyclohexene - cas 591-49-1, synthesis, structure, density, melting point, boiling point Follow safety data sheets for MEK and Acetone for more information on proper safety and handling. Specific Hazards: Can be ignited easily by heat, sparks, or flame and burns vigorously. 2-Methylcyclohexanol, mixture of cis and trans 99 209-512-0 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: viscous liquid. Flash Point: 58 deg C. Warning! Flammable liquid and vapor. Harmful if inhaled. May cause eye, skin, and respiratory tract irritation. Molecular Weight 98.19. Label elements Hazardous components which must be listed on the label methylcyclohexane Triacetoxymethylsilan Signal word: Danger Pictograms: Material Safety Data Sheet or SDS for Methylcyclohexane 806147 from Merck for download or viewing in the browser. Found inside... 1.2 % 400 ppm Methyl chloromethyl ether - See Chloromethyl methyl ether Methylcyclohexane Cyclohexylmethane , Hexahydrotoluene ( 2000 mg / m " ) CH. Ingestion May be harmful if swallowed. Found inside – Page 3283 ane , methylcyclohexane , and certain derivatives of these compounds . II . Inhalation . J Ind systemic effects in humans , probably There are no reports of chronic or Hyg Toxicol 25 : 323–347 , 1943 3. Treon JF , Crutchfield WE Jr , Kitzmiller ... 1-Ethyl-4-methylcyclohexane; Cyclohexane, 1-ethyl-4-methyl-, trans-Other names: cis-1-Ethyl-4-Methylcyclohexane; cis-1-Methyl-4-Ethylcyclohexane; 1-Methyl-cis-4-ethylcyclohexane; 1-Ethyl-4-methyl(cis)-cyclohexane; c-1-Ethyl-4-methylcyclohexane; 1-Ethyl-4-methylcyclohexane, (Z)- Permanent link for this species. May be harmful if swallowed. Methylcyclohexane for synthesis. First-aid measures Hazards identification Classification of the substance or mixture: GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. MATERIAL SAFETY DATA SHEET NAME OF PRODUCT: Aspirin MSDS DATE: 06 Jun, 2011 Notice NSF Reference Standards are for test and assay use only and are not intended for human or animal consumption. Solvent vapours can be inhaled or absorbed through the skin, passing into the blood stream. Found inside – Page 622 9.1 4 18 Methylcyclohexane (108-87-21 (1987)............................ 400 1610 Methylcyclohexanol ... 62 FUNDAMENTALS OF HAZARDOUS MATERIALS INCIDENTS. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Found inside – Page 1924... (Methyl 2-butenoate), 1795 Methylcyclobutane, 1826 Methylcyclohexane, 2671 3-Methylcyclohexanone, 2660 4-Methylcyclohexanone, 2661 4-Methylcyclohexene, ... : 2296 IMCO Class No. Found inside – Page 8-60Hazardous Chemical Data Manual ... 3 - Methylbutyraldehyde Methylcarbamate Methylchloroform Methylcyclohexane 2 - Methylcyclohexanol 0 - Methylcyclohexanone ... We provide 1-CHLORO-1-METHYLCYCLOHEXANE safety data sheets view and download at Echemi.com. May cause respiratory tract irritation. METHYLCYCLOHEXANE 108 -87 -2 0 - 20% N-HEPTANE 142 -82 -5 30 - 45% * All concentrations are percent by weight unless material is a gas. Safety glasses with side-shields conforming to EN166.
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